I mostly use the same tools as in OS X (FF, OOo, bash, SSH, VLC, mplayer)
Linux-specific (kind of) apps/tools. Basically stuff that I miss

:
Amarok: best media player ever (using it @OS X is not so great, though)
K3b: burning
Shorewall / iptables: firewall. ipfw is nice but it causes my system to freeze. Shorewall is a config file based front-end for iptables.
KTorrent: one of the best torrent clients (second to µTorrent for Windows)
PulseAudio: network-enabled audio server
libflac/libvorbis: support for all codecs without dirty and user-ufriendly hacks like Fluke
VPDAU: Let the GPU render my H.264 1080p

kioslaves: Full Network transparancy in all kde-apps